https://nova.newcastle.edu.au/vital/access/ /manager/Index en-au 5 High-resolution synchrotron X-ray fluorescence investigation of calcite coralloid speleothems: elemental incorporation and their potential as environmental archives https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:48378 Wed 15 Mar 2023 13:55:00 AEDT ]]> The influence of Antarctic subglacial volcanism on the global iron cycle during the last glacial maximum https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:30180 2 drawdown during the last glacial period were linked to iron (Fe) fertilization of subantarctic surface waters. The principal source of this Fe is thought to be dust transported from southern mid-latitude deserts. However, uncertainty exists over contributions to CO2 sequestration from complementary Fe sources, such as the Antarctic ice sheet, due to the difficulty of locating and interrogating suitable archives that have the potential to preserve such information. Here we present petrographic, geochemical and microbial DNA evidence preserved in precisely dated subglacial calcites from close to the East Antarctic Ice-Sheet margin, which together suggest that volcanically-induced drainage of Fe-rich waters during the Last Glacial Maximum could have reached the Southern Ocean. Our results support a significant contribution of Antarctic volcanism to subglacial transport and delivery of nutrients with implications on ocean productivity at peak glacial conditions.]]> Wed 11 Apr 2018 17:19:42 AEST ]]> Glacio-lacustrine aragonite deposition, meltwater evolution and glacial history during isotope stage 3 at Radok Lake, Amery Oasis, Northern Prince Charles Mountains, East Antarctica https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:3370 Wed 11 Apr 2018 12:19:35 AEST ]]> Petrographical and geochemical changes in Bosnian stalagmites and their palaeo-environmental significance https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:31155 Wed 11 Apr 2018 11:49:04 AEST ]]> Speleothem climate records from deep time? exploring the potential with an example from the Permian https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:11218 Wed 11 Apr 2018 10:32:36 AEST ]]> Exploring the dating of "dirty" speleothems and cave sinters using radiocarbon dating of preserved organic matter https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:30186 14C ages ranged from 2232 to 2889 cal yr BP, with 95.4% probability age range in the youngest and oldest samples of 2153–2337 and 2342–3449 cal yr BP respectively. The median age of the more modern dripstone was 336 cal yr BP, with a 95.4% probability age range of 148–486 cal yr BP. These results provide very approximate ball-park estimates of the age of the sample, but are consistently too old when compared to the known maximum ages of formation. It is hypothesised that this offset is due to a combination of the nature of the organic carbon transported from the source organic matter pools, and reworking of both modern and old organic carbon by in situ microbial communities.]]> Wed 04 Sep 2019 09:39:24 AEST ]]> U-Pb geochronology of speleothems by MC-ICPMS https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:1234 Sat 24 Mar 2018 08:28:33 AEDT ]]> Late Holocene drought responsible for the collapse of Old World civilizations is recorded in an Italian cave flowstone https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:1222 Sat 24 Mar 2018 08:28:30 AEDT ]]> Stalagmite carbon isotopes and dead carbon proportion (DCP) in a near-closed-system situation: an interplay between sulphuric and carbonic acid dissolution https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:30183 2 contribution to the total dissolved inorganic carbon (DIC). Pronounced millennial-scale shifts in DCP and relatively small coeval but antipathetic changes in δ¹³C are modulated by the effects of hydrological variability on open and closed-system dissolution, SAD and prior calcite precipitation. Hence, the DCP in Corchia Cave speleothems represents an additional proxy for rainfall amount.]]> Sat 24 Mar 2018 07:41:34 AEDT ]]> Robust chronological reconstruction for young speleothems using radiocarbon https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:26051 230Th relative even to the very low levels of detrital 230Th present. Here, we present an alternative method for reliable dating of these young speleothems using radiocarbon. Approximately 100 carbonate samples from SC4 and WM7 were analysed for 14C by accelerator mass spectrometry (AMS). The AMS results indicate that bomb 14C was evident in the youngest parts of both stalagmites. Two different approaches were used to estimate dead carbon fraction (DCF) values for these stalagmites for the pre-bomb period. For SC4, the DCF values were estimated based on the timing of 14C dates for that period determined by high-resolution δ18O recorded in the speleothem, and the timing of the onset of bomb 14C. For WM7, a “maximum” range of pre-bomb DCF was determined. Chronologies of these speleothems were built based on a dense sequence of DCF-corrected ages using three different age-depth models: Clam (Classical method), and Bacon and OxCal (Bayesian statistical approach). Good agreement between these age-depth models were observed indicating that the top 170 mm of SC4 and the top 50 mm of WM7 grew during the past 550–750 years and 1360–1740 years, respectively.]]> Sat 24 Mar 2018 07:31:29 AEDT ]]> "Cryptic" diagenesis and its implications for speleothem geochronologies https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:25047 Sat 24 Mar 2018 07:10:46 AEDT ]]> Effect of aragonite to calcite transformation on the geochemistry and dating accuracy of speleothems. An example from Castañar Cave, Spain https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:35499 Mon 13 Mar 2023 15:06:27 AEDT ]]> High spatial resolution investigation of nucleation, growth and early diagenesis in speleothems as exemplar for sedimentary carbonates https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47225 Fri 16 Dec 2022 10:37:32 AEDT ]]>